The Role of Tin in Glass System (89 - 104)

Authors

  • M.M. Abd Karim
  • A.K. Ariffin
  • D. Holland

Keywords:

Glass system, glass structure, glass formation, modifier, intermediate, tin, stannous silicates, stannous borates, stannous germanates, stannousfluorophosphate

Abstract

Tin constitutes a minor component in commercially produced flat and container glasses.Divalent, tetravalent and tin metal diffused into the surface of the glass during productionand strengthened the chemical and physical properties of these glasses. Tetravalent tinhas a low solubility in any glass system but divalent tin can formed glasses with a highSn2+ content in borate, germanate, phosphate, and silicate glass systems. This papersurveyed past studies of the roles of tin in glass systems that contained tin. The differentstructural roles of Sn2+ and Sn4+ in various glass systems surveyed are discussed in termof the structural difference between divalent and tetravalent of tin compounds in the glass systems, which were reflected in the results of spectroscopic and physical propertiesstudies of the glasses. Divalent tin has been shown to fulfill various structural roles aseither modifier or intermediate, depending on the type of glass system and composition.

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Published

2014-06-18

How to Cite

Karim, M. A., Ariffin, A., & Holland, D. (2014). The Role of Tin in Glass System (89 - 104). EDUCATUM Journal of Science, Mathematics and Technology, 1(1), 89–104. Retrieved from https://ejournal.upsi.edu.my/index.php/EJSMT/article/view/16