Preparation of Zinc Layered Hydroxides-cinnamaldehyde Nanocomposites and Its Physico-Chemical Study
DOI:
https://doi.org/10.37134/ejsmt.vol4.1.5.2017Keywords:
layered hydroxides, intercalation, cinnamaldehyde, nanocompositesAbstract
Cinnamaldehyde (CINN) is an organic guest anion, the main constituent of cinnamon oil was intercalated into zinc-layered hydroxides (ZLHs) by ion exchange method. CINN has been reported can killed mosquito larvae. The powder X-Ray diffraction (PXRD) indicates a successful intercalation of CINN into the interlayer galleries of ZLHs matrix when 1.0 g of ZnO with 0.08M of CINN was used forming zinc layered hydroxides-cinnamaldehyde (ZCINN) exhibiting basal spacing expansion, 21.2Å. Fourier transform infrared (FTIR) results supported and confirmed the intercalation of CINN as both ZnO and CINN functional groups appeared in ZCINN spectrum. The thermal stability property of the ZCINN was enhanced as compared to the anion, CINN. Field emission scanning electron microscopy (FESEM) image of ZnO showed a nonuniform granular-like structure transforming into flaky structure with various sizes after intercalation of CINN took place. These results indicate that it is possible to design and develop the nanocomposites containing larvicide for further investigations.
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References
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Mohsin, S. M. N., Hussein, M. Z., Sarijo, S. H., Fakurazi, S., Arulsevan, P., Taufiq, Y. Y. H. (2013). Synthesis of (cinnamate-zinc layered hydroxides) intercalation compound for sunscreen application. Chemistry Central
Journal. 7; 26.
Hashim, N., Hussein, M. Z., Isa, I. M., Kamari, A., Mohamed, A., Jaafar, A. M., Taha, H. (2014). Characterization and controlled release formulation of agrochemical herbicides based on Zinc-Layered-Hydroxides-3-(4- Methoxyphenyl) Propionate Nanocomposites. Journal of Physical and Chemical Sciences. VII4.DOI: 10.15297/JPCS.VII4.03.
Khan, S.B., Liu, C., Jang, E.S., Akhtar, K. and Han, H. (2011). Encapsulation of organic UV ray adsorbents into layered double hydroxide for photochemical properties. Materials Letters. 65; 2923-2926.
Hussein, M. Z., Ali, S. H. A., Zainal, Z., Hakim, M. N. (2011). Development of antiproliferativenanohybrid
compound with controlled release property using ellagic acid as the active agent. Int J Nanomed. 6:1373-1383.
Abdul Latip, A.F., Hussein, M.Z., Stanslas, J., Charng, C.W. and Adnan, R. (2013). Release behavior and toxicity profiles towards A549 cell lines of ciprofloxacin from its layered zinc hydroxides intercalation compound. Chemistry Central Journal. 7:119.
Kandare, E., Chigwada, G., Wang, D., Wilkie, C. A., Hossenlopp, J. M. (2006). Probing synergism, antogonism,
and additive effects in poly(vinyl ester) (PVE) composites with fire retardants. PolymDegrad Stab. 91:1209- 1218.
Cordeiro, C.S., Arizaga, G.G.C., Ramos, L.P., and Wypch, F. (2008). A new zinc hydroxide nitrate heterogeneous catalyst for the esterification of free fatty acids and the tranesterification of vegetable oils. Catalyst Communication. 9:2140-.2143.
Li, J. Li, Y. and Dong, H. (2008). Controlled release of herbicide acetochlor from clay/carboxylmethylcellulose
gel formulations. Journal of Agricultural and Food Chemistry. 56; 1336-1342.
Wei, M., He, J., Li, B., Evans, D. G., Duan, X. (2006). Preparation of layered double hydroxides. Struct. Bond.
119: 89-119.
Cheng, S. -S., Liu, J. -Y., Tsai, K. -H., Chen, W. -J., Chang, S. -T. (2004). Chemical Composition and Mosquito
Larvicidal Activity of Essential Oils from Leaves of Different Cinnamon osmophloem Provenances. J. Agric.
Food Chem. 52; 4395-4400.
Lee, H. C., Cheng, S. S., Chang, S. T. (2005). Antifungal property of the essential oils and their constituent from Cinnamomumosmopholeumleaf against tree pathogenic fungi. J. Sci. Food Agric. 85: 2047-2053.
Wang, S. Y., Chen, P. F., Chang, S. T. (2005). Antifungal activities of essential oils and their constituents from
indigenous cinnamon (Cinnamomumosmopholeum) leaves against wood decay fungi. Bioresour. Technol. 96:
813-818.
Chao, L. K., Hua, K. F., Hsu, H.Y., Cheng, S. S., Lin, I. F., Tsai, R. Y., Chen, S. T., Chang, S. T. (2008). Cinnamaldehyde inhibits pro-inflammatory cytokines secretion from monocytes/macrophages through suppression of intracellular signaling. Food Chem. Toxicol. 46: 220-231.
Newman S. P., and Jones, W. Comparative study of some layered hydroxide salts containing exchangeable
interlayer anions. Journal of Solid State Chemistry, vol. 148, no. 1, pp. 26–40, 1999.
Nabipour H. and Sadr, M. H., Controlled release of Diclofenac, an anti-inflammatory drug by nanocompositing
with layered zinc hydroxide. Journal of Porous Materials, vol. 22, no. 2, pp. 447–454, 2015.
Munoz-Espi, R., Chandra, A. and Wegner, G. (2007). Crystal perfection in zinc oxide with occluded carboxylfunctionalised latex particles. Cryst Growth Des. 7:1584-1589.
Richardson-Chong, S.S.D, Patel, R. and Williams, G.R. (2012). Intercalation and controlled release of bioactive
ions using a hydroxyl double salt. IndEngChem Res. 51:2913-2921.
Sarijo, S.H., Hussein, M.Z.B., Yahya, A.H. Zainal, Z. and Yarmo, M.A. (2010). Synthesis of phenoxyherbicides-intercalated layered double hydroxidnanohybrids and their controlled release property. Current Nanoscience. Vol 6, no 2, pp. 199-205.
Cavani, F., Trifirò, F. and Vaccari, A. (1991). Hydrotalcite-type anionic clays: preparation and applications.
Catalysis Today. 11 (2): 173-301.
Hussein Al Ali, S.H., Al-Qubaisi, M., Hussein, M.Z., Zainal, Z. and Hakim, M.M. (2011). Preparation of hippurate-zinc layered hydroxide nanohybrid and its synergistic effect with tamoxifen on HepG2 cell lines. International Journal of Nanomedicine. 6:3099-3111.
Rozita Ahmad, Hussein, M.Z., Sarijo, S.H., Wan Abdul Kadir, W.R. and Taufiq, Y.Y.H. (2016). Synthesis and
characteristics of valeric acid-zinc layered hydroxide intercalation material for insect pheromone control release
formulation. Journal of Materials. Article ID 1285721.
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Published
2017-06-19
How to Cite
Mohamad Jaafar, A., Jamaluddin, N. J., & Saidi, N. A. (2017). Preparation of Zinc Layered Hydroxides-cinnamaldehyde Nanocomposites and Its Physico-Chemical Study. EDUCATUM Journal of Science, Mathematics and Technology, 4(1), 34–40. https://doi.org/10.37134/ejsmt.vol4.1.5.2017
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