Coordination Chemistry of the Benzaldehyde−(1R)−(-)−Fenchone Azine and Derivatives Fench=NN=C(H)−C6H4X (X = H, Cl, Br, OMe or NO2 in the Meta or Para Positions) with Palladium

Authors

  • Mustaffa Ahmad
  • Illyas Md Isa
  • Bernard L. Shaw
  • Sarath D. Perera

Keywords:

Fenchone azine, chiral terpene, palladium complexes

Abstract

The benzaldehyde−(1R)−(-)−fenchone azine (1) and derivatives (3), (4), (5), (6) and (7) were prepared by heating the desired benzaldehyde derivatives and fenchone hydrazone in boiling ethanol solution in the presence of acetic acid as catalyst for 3 h. Treatment of the ligands (L) with Na2PdCl4H2O or [PdCl2(NCPh)2] in the ratio of 1 : 1 or 2 : 1 gave the complexes of the type PdL2Cl2 (2), (8), (9), (10), (11) and (12) of which the palladium was bonded to the nitrogen near to fenchone residue.

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Author Biographies

Mustaffa Ahmad

Deparment of Chemistry, Faculty of Science and Technology,
Universiti Pendidikan Sultan Idris, 35900 Tanjong Malim, Perak. Malaysia

Illyas Md Isa

Deparment of Chemistry, Faculty of Science and Technology,
Universiti Pendidikan Sultan Idris, 35900 Tanjong Malim, Perak. Malaysia

Bernard L. Shaw

School of Chemistry, University of Leeds, Leeds LS2 9JT, UK

Sarath D. Perera

School of Chemistry, University of Leeds, Leeds LS2 9JT, UK

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Published

2009-06-17

How to Cite

Ahmad, M., Md Isa, I., L. Shaw, B., & D. Perera, S. (2009). Coordination Chemistry of the Benzaldehyde−(1R)−(-)−Fenchone Azine and Derivatives Fench=NN=C(H)−C6H4X (X = H, Cl, Br, OMe or NO2 in the Meta or Para Positions) with Palladium. Journal of Science and Mathematics Letters, 1(1), 11–21. Retrieved from https://ejournal.upsi.edu.my/index.php/JSML/article/view/321

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